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Abstract We present high-resolutionK-band emission spectra of the quintessential hot Jupiter HD 189733 b from the Keck Planet Imager and Characterizer. Using a Bayesian retrieval framework, we fit the dayside pressure–temperature profile, orbital kinematics, mass-mixing ratios of H₂O, CO, CH₄, NH₃, HCN, and H₂S, and the¹³CO/¹²CO ratio. We measure mass fractions of ${\mathrm{logH}}_2\mathrm{O}=-{2.0}_{-0.4}^{+0.4}$and $\mathrm{logCO}=-{2.2}_{-0.5}^{+0.5}$, and place upper limits on the remaining species. Notably, we find logCH₄< −4.5 at 99% confidence, despite its anticipated presence at the equilibrium temperature of HD 189733 b assuming local thermal equilibrium. We make a tentative (∼3σ) detection of¹³CO, and the retrieved posteriors suggest a¹²C/¹³C ratio similar to or substantially less than the local interstellar value. The possible¹³C enrichment would be consistent with accretion of fractionated material in ices or in the protoplanetary disk midplane. The retrieved abundances correspond to a substantially substellar atmospheric C/O = 0.3 ± 0.1, while the carbon and oxygen abundances are stellar to slightly superstellar, consistent with core-accretion models which predict an inverse correlation between C/O and metallicity. The specific combination of low C/O and high metallicity suggests significant accretion of solid material may have occurred late in the formation process of HD 189733 b. 

Abstract We present Keck Planet Imager and Characterizer (KPIC) high-resolution (R∼35,000)K-band thermal emission spectroscopy of the ultrahot Jupiter WASP-33b. The use of KPIC’s single-mode fibers greatly improves both blaze and line-spread stabilities relative to slit spectrographs, enhancing the cross-correlation detection strength. We retrieve the dayside emission spectrum with a nested-sampling pipeline, which fits for orbital parameters, the atmospheric pressure–temperature profile, and the molecular abundances. We strongly detect the thermally inverted dayside and measure mass-mixing ratios for CO ( ${\mathrm{logCO}}_{\mathrm{MMR}}=-{1.1}_{-0.6}^{+0.4}$), H₂O ( ${\mathrm{logH}}_2{\mathrm{O}}_{\mathrm{MMR}}=-{4.1}_{-0.9}^{+0.7}$), and OH ( ${\mathrm{logOH}}_{\mathrm{MMR}}=-{2.1}_{-1.1}^{+0.5}$), suggesting near-complete dayside photodissociation of H₂O. The retrieved abundances suggest a carbon- and possibly metal-enriched atmosphere, with a gas-phase C/O ratio of ${0.8}_{-0.2}^{+0.1}$, consistent with the accretion of high-metallicity gas near the CO₂snow line and post-disk migration or with accretion between the soot and H₂O snow lines. We also find tentative evidence for¹²CO/¹³CO ∼ 50, consistent with values expected in protoplanetary disks, as well as tentative evidence for a metal-enriched atmosphere (2–15 × solar). These observations demonstrate KPIC’s ability to characterize close-in planets and the utility of KPIC’s improved instrumental stability for cross-correlation techniques. 

Abstract We present medium-resolution ( λ /Δ λ  = 2700), near-infrared spectral standards for field L0–L2, L4, and L7–Y0 dwarfs obtained with the Near-Infrared Echellette Spectrometer on the Keck II 10 m telescope. These standards allow for detailed spectral comparative analysis of cold brown dwarfs discovered through ongoing ground-based projects such as Backyard Worlds: Planet 9, and forthcoming space-based spectral surveys such as the James Webb Space Telescope, SPHEREx, Euclid, and the Nancy Grace Roman Space Telescope. 

NIRSPEC is a high-resolution near-infrared echelle spectrograph on the Keck II telescope that was commissioned in 1999 and upgraded in 2018. This recent upgrade was aimed at improving the sensitivity and longevity of the instrument through the replacement of the spectrometer science detector (SPEC) and slit-viewing camera (SCAM). Commissioning began in 2018 December, producing the first on-sky images used in the characterization of the upgraded system. Through the use of photometry and spectroscopy of standard stars and internal calibration lamps, we assess the performance of the upgraded SPEC and SCAM detectors. First, we evaluate the gain, readnoise, dark current, and the charge persistence of the spec detector. We then characterize the newly upgraded spectrometer and the resulting improvements in sensitivity, including spectroscopic zero points, pixel scale, and resolving power across the spectrometer detector field. Finally, for SCAM, we present zero points, pixel scale, and provide a map of the geometric distortion of the camera. 

Exoplanets are abundant in our galaxy and yet characterizing them remains a technical challenge. Solar System planets provide an opportunity to test the practical limitations of exoplanet observations with high signal-to-noise data that we cannot access for exoplanets. However, data on Solar System planets differ from exoplanets in that Solar System planets are spatially resolved while exoplanets are unresolved point-sources. We present a novel instrument designed to observe Solar System planets as though they are exoplanets, the Planet as Exoplanet Analog Spectrograph (PEAS). PEAS consists of a dedicated 0.5-m telescope and off-the-shelf optics, located at Lick Observatory. PEAS uses an integrating sphere to disk-integrate light from the Solar System planets, producing spatially mixed light more similar to the spectra we can obtain from exoplanets. This paper describes the general system design and early results of the PEAS instrument. 

Abstract Direct imaging studies have mainly used low-resolution spectroscopy ( R ∼ 20–100) to study the atmospheres of giant exoplanets and brown dwarf companions, but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances (e.g., carbon-to-oxygen ratio, metallicity). This precludes clear insights into the formation mechanisms of these companions. The Keck Planet Imager and Characterizer (KPIC) uses adaptive optics and single-mode fibers to transport light into NIRSPEC ( R ∼ 35,000 in the K band), and aims to address these challenges with high-resolution spectroscopy. Using an atmospheric retrieval framework based on petitRADTRANS , we analyze the KPIC high-resolution spectrum (2.29–2.49 μ m) and the archival low-resolution spectrum (1–2.2 μ m) of the benchmark brown dwarf HD 4747 B ( m = 67.2 ± 1.8 M Jup , a = 10.0 ± 0.2 au, T eff ≈ 1400 K). We find that our measured C/O and metallicity for the companion from the KPIC high-resolution spectrum agree with those of its host star within 1 σ –2 σ . The retrieved parameters from the K -band high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum are highly sensitive to our chosen cloud model. Finally, we detect CO, H 2 O, and CH 4 (volume-mixing ratio of log(CH 4 ) = −4.82 ± 0.23) in this L/T transition companion with the KPIC data. The relative molecular abundances allow us to constrain the degree of chemical disequilibrium in the atmosphere of HD 4747 B, and infer a vertical diffusion coefficient that is at the upper limit predicted from mixing length theory. 

Abstract M dwarfs are common host stars to exoplanets but often lack atmospheric abundance measurements. Late-M dwarfs are also good analogs to the youngest substellar companions, which share similarT_eff∼ 2300–2800 K. We present atmospheric analyses for the M7.5 companion HIP 55507 B and its K6V primary star with Keck/KPIC high-resolution (R∼ 35,000)K-band spectroscopy. First, by including KPIC relative radial velocities between the primary and secondary in the orbit fit, we improve the dynamical mass precision by 60% and find $M_B={88.0}_{-3.2}^{+3.4}{M}_{\mathrm{Jup}}$, putting HIP 55507 B above the stellar–substellar boundary. We also find that HIP 55507 B orbits its K6V primary star with $a={38}_{-3}^{+4}$au ande= 0.40 ± 0.04. From atmospheric retrievals of HIP 55507 B, we measure [C/H] = 0.24 ± 0.13, [O/H] = 0.15 ± 0.13, and C/O = 0.67 ± 0.04. Moreover, we strongly detect¹³CO (7.8σsignificance) and tentatively detect ${\mathrm{H}}_2^{18}\mathrm{O}$(3.7σsignificance) in the companion’s atmosphere and measure ${}^{12}\mathrm{CO}{/}^{13}\mathrm{CO}={98}_{-22}^{+28}$and ${\mathrm{H}}_2^{16}\mathrm{O}/{\mathrm{H}}_2^{18}\mathrm{O}={240}_{-80}^{+145}$after accounting for systematic errors. From a simplified retrieval analysis of HIP 55507 A, we measure ${}^{12}\mathrm{CO}{/}^{13}\mathrm{CO}={79}_{-16}^{+21}$and ${\mathrm{C}}^{16}\mathrm{O}/{\mathrm{C}}^{18}\mathrm{O}={288}_{-70}^{+125}$for the primary star. These results demonstrate that HIP 55507 A and B have consistent¹²C/¹³C and¹⁶O/¹⁸O to the <1σlevel, as expected for a chemically homogeneous binary system. Given the similar flux ratios and separations between HIP 55507 AB and systems with young substellar companions, our results open the door to systematically measuring¹³CO and ${\mathrm{H}}_2^{18}\mathrm{O}$abundances in the atmospheres of substellar or even planetary-mass companions with similar spectral types.